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5,10-Diphenyltripyrrane, a useful building block for the synthesis of meso-phenyl substituted expanded macrocycles

Title5,10-Diphenyltripyrrane, a useful building block for the synthesis of meso-phenyl substituted expanded macrocycles
Publication TypeJournal Article
Year of Publication1997
AuthorsBruckner, C, Sternberg, ED, Boyle, RW, Dolphin, D
JournalChemical Communications
Pagination1689-1690
Date PublishedSep
Type of ArticleArticle
ISBN Number1359-7345
KeywordsPORPHOCYANINES, PORPHYRIN
Abstract

Pyrrole and benzaldehyde were condensed under acidic conditions to produce a mixture of 5-phenyldipyrromethane and 5,10-diphenyltripyrrane; the tripyrrane was utilized in syntheses of meso-phenylsapphyrins, meso-diphenylpentaphyrin and meso-hexaphenylhexaphyrin.
URL<Go to ISI>://A1997XW02200050