Title | Stoichiometric O-2 oxidation of bis(thioether) (octaethylporphyrinato)ruthenium(II) complexes to the corresponding sulfoxide species in acidic media. Structural confirmation of S-bonded sulfoxides |
Publication Type | Journal Article |
Year of Publication | 1999 |
Authors | Pacheco, A, James, BR, Rettig, SJ |
Journal | Inorganic Chemistry |
Volume | 38 |
Pagination | 5579-5587 |
Date Published | Nov |
Type of Article | Article |
ISBN Number | 0020-1669 |
Keywords | ACETONITRILE SOLUTION, CRYSTAL, ELECTRON-TRANSFER, LIGANDS, MOLECULAR-STRUCTURE, porphyrins, RUTHENIUM(II) |
Abstract | {Exposure to o(2) (or air) of a CH2Cl2, benzene, or toluene solution containing PhCO2H and Ru(OEP)(RR’S)(2) (where OEP = the dianion of 2,3,7,8,12,13,17,1 8-octaethylporphyrin |
URL | <Go to ISI>://000084047000016 |
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