Title | SOLVATION DYNAMICS IN ELECTROLYTE-SOLUTIONS |
Publication Type | Journal Article |
Year of Publication | 1994 |
Authors | Chandra, A, Patey, GN |
Journal | Journal of Chemical Physics |
Volume | 100 |
Pagination | 1552-1558 |
Date Published | Jan |
Type of Article | Article |
ISBN Number | 0021-9606 |
Keywords | DIELECTRIC-RELAXATION, INVARIANT EXPANSION, ION, LIQUIDS, MEAN SPHERICAL MODEL, ORNSTEIN-ZERNIKE EQUATION, SIMULATIONS, SOLVENT, SPHERES |
Abstract | A microscopic theory of the dynamics of ion solvation in electrolyte solutions is given. Consistent with the pure solvent case, the theory predicts a very fast and important inertial relaxation at short times. This is followed by oscillations and an extremely slow long-time decay associated with the formation of an equilibrium ’’ion atmosphere’’ about the newly charged particle. |
URL | <Go to ISI>://A1994MT00700085 |